A complex litter material for collecting liquid and solid excrements of domestic animals is made as a mixture of particles of clinoptilolite tuff and comprises clinoptilolite and montmorillonite, and particles of benthonite clay with the predominant content of montmorillonite. The said particles as a whole are covered with a layer of protective material which limits entering of air and moisture thereto and is made in such a manner as to allow removing thereof for the direct use of the litter material according to purpose thereof.